The Mantle of Siroria comes in 2 versions, an imperfect and a perfect version. The perfect version is slightly stronger in terms of stats than the imperfect version. The 5-piece bonus does the same thing on both versions.
The Mantle of Siroria set is part of the Summerset Chapter. You can acquire the set in the Cloudrest Mini-Trial in Summerset. Each set item is bound on pickup. You can acquire light armor, weapons and jewelry of this set in the Welkynar motif style.