Troll King is a Monster Set (Helm and Shoulder) available in light, medium or heavy armor. It drops in the Troll King (unique) style.
The 1-piece set bonus adds 4% Healing Done.
2-piece set bonus: When you heal a friendly target, if they are still below 50% Health, their Health Recovery is increased by 1548 for 10 seconds.
The Shoulder can be acquired by using an Undaunted key on Glirion the Redbeard's chest. The Shoulder type, weight and trait are RNG based and can be from any dungeon this NPC gives Pledges for.
The Helm can be acquired from Blessed Crucible which is part of the base game and located in The Rift. The Helm is guaranteed to drop from the final boss in veteran mode only. The weight and trait are RNG based.
You can mix-and-match Monster Set shoulders and helms from different sets and add two 1-piece bonuses to your build, or wear a complete set to take advantage of the full 2-piece set bonus.